Abstract:
Thiophene nucleus has been established as the potential entity in the large growing chemical world of
heterocyclic compounds possessing promising coupling characteristics. A series of coupler 4-aryl-2-aminothiophene-3-
carbonitrile derivatives were synthesized. The synthetic method involves the reaction of ketones, aldehydes or 1,3-
dicarbonyl species with activated nitriles and elemental sulphur in the presence of an amine base. Characterization of
these coupling components was carried out by UV-Visible spectroscopy, Fourier-transform infrared spectroscopy (FTIR), gas chromatography–mass spectrometry (GC-MS) and nuclear magnetic resonance spectroscopy (NMR) analysis.
The synthesized compounds were purified, characterized and evaluated for spectroscopic properties. They were found
to possess good coupling properties as well as high degree of brightness and a colour deepening effect compared to
other heterocyclic couplers.
